Oxidative cleavage of cycloalkenes using hydrogen peroxide and a tungsten-based catalyst: towards a complete mechanistic investigation
نویسندگان
چکیده
The identification of intermediates and by-products issuing from the oxidative cleavage cycloolefins allows proposing a reaction mechanism.
منابع مشابه
Selective oxidation of sulfides to sulfoxides by a vanadium-based catalyst using 30% hydrogen peroxide
The vanadium-based catalyst, acts as a homogeneous catalyst for the selective oxidation of various kinds of sulfides with 30% aqueous H2O2. Vanadium-based catalyst was successfully used as the oxygen source for the oxidation of sulfides to sulfoxides for the first time. The sulfoxides were obtained in a good way to high yields without any detectable over-oxidation to sulfones under normal condi...
متن کاملSelective oxidation of sulfides to sulfoxides by a vanadium-based catalyst using 30% hydrogen peroxide
The vanadium-based catalyst, acts as a homogeneous catalyst for the selective oxidation of various kinds of sulfides with 30% aqueous H2O2. Vanadium-based catalyst was successfully used as the oxygen source for the oxidation of sulfides to sulfoxides for the first time. The sulfoxides were obtained in a good way to high yields without any detectable over-oxidation to sulfones under normal condi...
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چکیده ندارد.
Oxidative desulfurization of light fuel oil by using hydrogen peroxide in the presence of acetic acid catalyst
Hydrogen peroxide as an oxidant agent was used for desulfurization of a petroleum hydrocarbon fraction (C10-C22) with boiling range of 175-375 ℃, (light fuel oil) in the presence of acetic acid as catalyst. The oxidation was performed in an ultrasonic bath. It is found that increasing the amount of hydrogen peroxide lead to increase the oxidation rate and so desulfurizatio...
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ژورنال
عنوان ژورنال: New Journal of Chemistry
سال: 2021
ISSN: ['1369-9261', '1144-0546']
DOI: https://doi.org/10.1039/d0nj03592k